全文获取类型
收费全文 | 21910篇 |
免费 | 4023篇 |
国内免费 | 3336篇 |
专业分类
化学 | 16543篇 |
晶体学 | 333篇 |
力学 | 1251篇 |
综合类 | 230篇 |
数学 | 2335篇 |
物理学 | 8577篇 |
出版年
2024年 | 30篇 |
2023年 | 490篇 |
2022年 | 624篇 |
2021年 | 833篇 |
2020年 | 977篇 |
2019年 | 1040篇 |
2018年 | 856篇 |
2017年 | 849篇 |
2016年 | 1108篇 |
2015年 | 1111篇 |
2014年 | 1312篇 |
2013年 | 1693篇 |
2012年 | 1939篇 |
2011年 | 2064篇 |
2010年 | 1487篇 |
2009年 | 1446篇 |
2008年 | 1472篇 |
2007年 | 1236篇 |
2006年 | 1201篇 |
2005年 | 1071篇 |
2004年 | 874篇 |
2003年 | 733篇 |
2002年 | 737篇 |
2001年 | 660篇 |
2000年 | 502篇 |
1999年 | 423篇 |
1998年 | 348篇 |
1997年 | 280篇 |
1996年 | 265篇 |
1995年 | 277篇 |
1994年 | 259篇 |
1993年 | 210篇 |
1992年 | 160篇 |
1991年 | 153篇 |
1990年 | 129篇 |
1989年 | 94篇 |
1988年 | 64篇 |
1987年 | 51篇 |
1986年 | 56篇 |
1985年 | 37篇 |
1984年 | 25篇 |
1983年 | 30篇 |
1982年 | 13篇 |
1981年 | 7篇 |
1980年 | 12篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1959年 | 3篇 |
1957年 | 4篇 |
1936年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
We proposed an electro-optic modulator with two-bus one-ring (TBOR) structure to improve the extinction ratio and reduce insert loss. It has a dual output compared with one-bus one-ring structure. In addition, double-layer graphene makes it possible for the modulation in the visible to mid-infrared wavelength range. It shows that this new electro-optic modulator can present two switching states well with low insertion loss, high absorption and high extinction ratio. At , when the switching states are based on the chemical potential, and , the insertion losses of both output ports are less than 2 dB, the absorption of the output port coupled via a micro-ring reaches 45 dB and the extinction ratio reaches 14 dB. When the refractive index of the dielectric material is 4.2, the applied voltage will be less than 1.2 V, thus can be used in low-voltage CMOS technology. 相似文献
72.
Jinhua Gao Yuanfang Tao Dr. Jian Zhang Nannan Wang Xin Ji Dr. Jinling He Prof. Yubing Si Prof. Weili Zhao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(48):11246-11256
Our previous discovery suggested that substituents on the 1,7 positions delicately modulate the sensing ability of the meso-arylmercapto boron-dipyrromethene (BODIPY) to biothiols. In this work, the impact of delicate modulations on the sensing ability is investigated. Therefore, 1,7-dimethyl, 3,5-diaryl substituted BODIPY is designed and developed and its conformationally restricted species with a meso-arylmercapto moiety ( DM-BDP-SAr and DM-BDP-R-SAr ) as selective fluorescent probes for Cys. Moreover, the lysosome-target probes ( Lyso-S and Lyso-D ) based on DM-BDP-SAr carrying one or two morpholinoethoxy moieties were developed. They were able to detect Cys selectively in vitro with low detection limits. Both Lyso-S and Lyso-D localized nicely in lysosomes in living HeLa cells and exhibited red fluorescence for Cys. Moreover, a novel fluorescence quenching mechanism was proposed from the calculations by density functional theory (DFT). The probes may go through intersystem crossing (from singlet excited state to triplet excited state) to result in fluorescence quenching. 相似文献
73.
Youping Lin Dr. Lei Wang Prof. Dr. Xin Huang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(72):16440-16450
Compartmentalisation is recognised to be a primary step for the assembly of non-living matter towards the construction of life-like microensembles. To date, a host of hollow microcompartments with various functionalities have been widely developed. Within this respect, given that dynamic behaviour is one of the fundamental features to distinguish living ensembles from those that are non-living, the design and construction of microcompartments with various dynamic behaviours are attracting considerable interest from a wide range of research communities. Significantly, the created dynamic microcompartments could also be widely used as chassis for further bottom-up design towards building protocell models by integrating and booting up necessary biological information. Herein, strategies to install the various motility behaviours into microcompartments, including haptotaxis, chemotaxis and gravitaxis, are summarized in the anticipation of inspiring more designs towards creating various advanced active microcompartments, and contributing new techniques to the ultimate goal of constructing a basic living unit entirely from non-living components. 相似文献
74.
Flexible control of building blocks of photonic crystals enables achieving desirable band structures. Exploration of photonic band extrema has brought many fantastic features to design artificial optical materials, such as Brillouin‐zone‐corner extrema for valley photonic materials and zone‐center extremum for zero‐index metamaterials. However, two such kinds of extrema are always found independently in different photonic crystals. In this work, a kind of valley photonic crystals possessing both zone‐center and zone‐corner band extrema almost at the same frequency is proposed. Inspired by antennas theory, a three‐antenna array (TAA) source is devoted to individually manipulate each extremum. The correlation coefficient is given to determine the coupling efficiency between the TAA source and extrema eigenmodes. By using a source with a high correlation coefficient, these extrema bulk states are selectively excited consistent with their eigenfields. Furthermore, three control cases are shown that multiple extrema points are simultaneously excited, in order to confirm the validity of the correlation coefficient. Finally, a potential application of a beam‐steering device is proposed through selective excitation of ternary extrema. This work develops binary valley states into ternary mix states, rendering more degrees of freedom for on‐chip optical information transport, particularly for beam steering and mode division multiplexing. 相似文献
75.
Kai He Tsegaye TadesseTsega Xi Liu Jiantao Zai Xin‐Hao Li Xuejiao Liu Wenhao Li Nazakat Ali Xuefeng Qian 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(34):12029-12035
The modulation of electron density is an effective option for efficient alternative electrocatalysts. Here, p‐n junctions are constructed in 3D free‐standing FeNi‐LDH/CoP/carbon cloth (CC) electrode (LDH=layered double hydroxide). The positively charged FeNi‐LDH in the space‐charge region can significantly boost oxygen evolution reaction. Therefore, the j at 1.485 V (vs. RHE) of FeNi‐LDH/CoP/CC achieves ca. 10‐fold and ca. 100‐fold increases compared to those of FeNi‐LDH/CC and CoP/CC, respectively. Density functional theory calculation reveals OH? has a stronger trend to adsorb on the surface of FeNi‐LDH side in the p‐n junction compared to individual FeNi‐LDH further verifying the synergistic effect in the p‐n junction. Additionally, it represents excellent activity toward water splitting. The utilization of heterojunctions would open up an entirely new possibility to purposefully regulate the electronic structure of active sites and promote their catalytic activities. 相似文献
76.
77.
Dr. Zhihe Qing Guoyan Luo Shuohui Xing Dr. Zhen Zou Dr. Yanli Lei Prof. Juewen Liu Prof. Ronghua Yang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(33):14148-14152
The Au−S bond is the classic way to functionalize gold nanoparticles (AuNPs). However, cleavage of the bond by biothiols and other chemicals is a long-standing problem hindering practical applications, especially in cells. Instead of replacing the thiol by a carbene or selenol for stronger adsorption, it is now shown that the Pt−S bond is much more stable, fully avoiding cleavage by biothiols. AuNPs were deposited with a thin layer of platinum, and an AuNP@Pt-S nanoflare was constructed to detect the miRNA-21 microRNA in living cells. This design retained the optical and cellular uptake properties of DNA-functionalized AuNPs, while showing high-fidelity signaling. It discriminated target cancer cells even in a mixed-cell culture system, where the Au-S based nanoflare was less sensitive. Compared to previous methods of changing the ligand chemistry, coating a Pt shell is more accessible, and previously developed methods for AuNPs can be directly adapted. 相似文献
78.
以典型的双稳态系统——屈曲梁结构为例,基于等效模型,结合解析、数值和实验手段,研究了双稳态结构中的1/2次谐波共振特性、演化过程、参数调节规律及其对隔振特性的影响.研究发现,当非线性刚度系数或激励幅值增加到一定程度时,系统会在一定带宽下产生显著的1/2次谐波共振;随着激励幅值增加,阻尼系统的1/2次谐波遵循“产生-增强-衰退-消失”的过程,该过程对峰值频率和峰值传递率有重要影响;适当提高非线性强度能有效改善双稳态结构隔振特性.针对双稳态屈曲梁结构开展的实验验证了1/2次谐波特性和隔振特性变化规律. 相似文献
79.
Su X. F. Zhang Y. L. Maximov A. L. Zhang K. Xin Q. Feng C. Q. Bai X. F. Wu W. 《Russian Journal of Applied Chemistry》2020,93(1):127-136
Russian Journal of Applied Chemistry - Nanoscale ZSM-5 (AlZ5-D) and Ga-substituted ZSM-5 zeolites ((Al,Ga)Z5-D and GaZ5-D) were synthesized by a green dry-gel conversion strategy. For comparison,... 相似文献
80.